Spider-Woman

Jessica Drew is the first heroine to be known by the name Spider-Woman! She is also a private detective, a member of the Intergalactic peace-keeping organization known as S.W.O.R.D., an agent of the international peace-keeping organization known as S.H.I.E.L.D., and a former agent of the terrorist cell known as HYDRA.

Earth's Mightiest
In the very first round of the first mini-tournament, Spider-Woman defeated fellow Avenger Hank Pym before being eliminated by fellow arachnid-hero, Spider-Man.